HYDROPHOBIC BEHAVIOR OF INSULATORS COATED WITH RTV SILICONE-RUBBER

Room temperature vulcanizing (RTV) silicone rubber coatings are applied to electrical insulators to improve their subsequent insulation strength, particularly under wet conditions. Under prolonged wetting the hydrophobicity of the coating is reduced temporarily and the insulator protection is lost. After a dry period, a recovery of the hydrophobicity takes place. To investigate this phenomenon, the surface was subjected to various wetting conditions with and without electrical stress. Measurements of the contact and the sliding angles were used to determine the state of the surface. Using water, the surface free energy-gamma(s) of the RTV was calculated from the contact angle measurements as a function of time of exposing the surface to salt-fog. The surface free energies due to London dispersion-gamma(SD), and hydrogen bonding-gamma(SH), forces on the surface of RTV coatings were calculated from the contact angle measurements using both water and methylene iodide. Good agreement was obtained with the literature value for a virgin RTV surface. To study the chemical changes on the surface of RTV, attenuated total reflection Fourier transform infrared spectroscopy and electron spectroscopy for chemical analysis were employed. The chemical changes of the surface are shown to be responsible for the loss of hydrophobicity.