ELECTRICAL-CONDUCTION MECHANISM IN SOLID ELECTROLYTES WITH ZIRCONIUM-PHOSPHATE FRAMEWORK

被引：7

作者：

IKEDA, S

NOMURA, K

ITO, K

EINAGA, H

机构：

[1] Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya, 466, Gokiso-cho

来源：

SOLID STATE IONICS | 1994年 / 70卷

关键词：

D O I：

10.1016/0167-2738(94)90301-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The difference in the electrical conduction behavior of various kinds of M(n)Zr2n(PO4)3n (M(n) = alkali metals, alkaline earth metals, Ag, Mn, Co, Ni, Zn, Cd, Pb, Al, Ga, and In) compounds (abbreviated as MZP) has been investigated by using frequency dispersion analysis. The conductivity of MZP with a NASICON-type structure mainly depended on the hopping rate of mobile cation; the conductivity of MZP with a beta-Fe2(SO2)3-type structure was more affected by the mobile ion concentration than that with the NASICON-type one. These conclusions agree well with those obtained from crystallographic investigation.

引用

页码：153 / 156

页数：4

共 18 条

[1] THE ACTIVATION ENTROPY FOR TRANSPORT IN IONIC CONDUCTORS [J].