PREPARATION AND PROPERTIES OF ORDERED AND RANDOM POLYAMIDE-ESTERS FROM 4-(4-AMINO-ALPHA,ALPHA-DIMETHYLBENZYL) PHENOL AND AROMATIC DIACYL CHLORIDES

被引：9

作者：

IMAI, Y ^{[1
]}

ABE, S ^{[1
]}

TAKAHASHI, T ^{[1
]}

UEDA, M ^{[1
]}

机构：

[1] YAMAGATA UNIV,FAC ENGN,DEPT POLYMER CHEM,YONEZAWA,YAMAGATA 992,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1982年 / 20卷 / 03期

关键词：

CATALYSTS - Chemistry - CHEMICAL REACTIONS - MONOMERS - Synthesis - POLYAMIDES - Molecular Structure - POLYESTERS - Physical Properties;

D O I：

10.1002/pol.1982.170200309

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In the reported experiments, random polyamide-esters were prepared directly by the interfacial and solution polycondensation of 4-(4-amino- alpha , alpha -dimethylbenzyl)phenol (I) with iso- and terephthaloyl chlorides. Authentic samples of ordered polyamide-esters with an amide-amide-ester-ester structure were synthesized by the two-step procedure; that is, the preparation of amide-bisphenol monomers from I and subsequent polycondensation with aromatic diacyl chlorides. The random and ordered polyamide-esters differed from one another with respect to solubility in organic solvents and glass transition temperature, whereas all the random and ordered polymers were of equal low crystallinity. All of these polymers began to decompose around 350 degree C in both air and nitrogen atmospheres.

引用

页码：683 / 689

页数：7

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