A NEW [ABCD -] ABCDE] CYCLOADDITION STRATEGY FOR THE APPROACH TO YOHIMBE ALKALOIDS - STEREOSELECTIVE SYNTHESIS OF (+/-)-3-EPI-ALLO-YOHIMBONE

被引：10

作者：

GOMEZPARDO, D

DANGELO, J

机构：

[1] FAC PHARM CHATENAY MALABRY,CNRS,CHIM ORGAN LAB,5 RUE JB CLEMENT,F-92296 CHATENAY MALABRY,FRANCE

[2] CNRS,ECOLE SUPER PHYS & CHIM IND,UNITE CHIM ORGAN,F-75231 PARIS,FRANCE

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 44期

关键词：

DIELS-ALDER CYCLOADDITION; YOHIMBE ALKALOIDS; (+/-)-3-EPI-ALLO-YOHIMBONE;

D O I：

10.1016/S0040-4039(00)61005-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diels-Alder cycloaddition between lactam-sulfone 9 and diene 10 led to adducts 11 + 12 (30 : 1, respectively). Compound 11 has been converted in 4 steps into (+/-)-3-epi-allo-yohimbone 16.

引用

页码：6637 / 6640

页数：4

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