Synthesis of methyl 2-O-, 3-O-, and 5-O-beta-D-ribofuranosyl-beta-dribofuranoside via 1,2-O-cyanoethylidene derivatives of D-ribofuranose

被引：2

作者：

Gass, Josef

Chkistian, Rudolf

Kosma, Paul ^{[1
]}

机构：

[1] Agr Univ Vienna, Inst Chem, A-1180 Vienna, Austria

[2] Sandoz Forschungsinst Wien, A-1235 Vienna, Austria

来源：

CARBOHYDRATE RESEARCH | 1988年 / 180卷 / 02期

关键词：

D O I：

10.1016/0008-6215(88)80081-8

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Triphenylmethylium perchlorate-catalyzed glycosylation of 2-, 3-and 5-trityl ethers of methyl ss-D-ribofuranoside by 1-2-O-cyanoethylidene derivatives of D-ribofuranose gave good yields of the corresponding 1,2-trans-linked disaccharide derivatives. The structural assignments of the deprotected disaccharides were confirmed by H-1-n.m.r.-and C-13-n.m.r. spectroscopy.

引用

页码：243 / 251

页数：9

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