ISOPRENE AND ITS OXIDATION-PRODUCTS - METHACROLEIN AND METHYL VINYL KETONE

被引：85

作者：

PIEROTTI, D

WOFSY, SC

JACOB, D

RASMUSSEN, RA

机构：

[1] HARVARD UNIV, DEPT EARTH & PLANETARY SCI, CAMBRIDGE, MA 02138 USA

[2] OREGON GRAD CTR, BEAVERTON, OR 97006 USA

来源：

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES | 1990年 / 95卷 / D2期

关键词：

D O I：

10.1029/JD095iD02p01871

中图分类号：

P4 [大气科学（气象学）];

学科分类号：

0706 ; 070601 ;

摘要：

The first measurements of methacrolein (MACR) and methyl vinyl ketone (MVK) in the atmosphere are reported. The compounds both show a strong seasonal variation, with a maximum in the summer. The concentrations of MACR and MVK are highly correlated with each other and with the concentration of isoprene, in accord with the expectation that they are the major initial products of isoprene oxidation. However, the observed MACR/MVK ratio does not agree with the model predictions over the range of conditions normally observed in the nonurban continental boundary layer. -from Authors

引用

收藏

页码：1871 / 1881

页数：11

相关论文

共 29 条

[1] REVIEW - NATURAL VOLATILE ORGANIC-SUBSTANCES AND THEIR EFFECT ON AIR-QUALITY IN THE UNITED-STATES [J].

ALTSHULLER, AP .

ATMOSPHERIC ENVIRONMENT, 1983, 17 (11) :2131-2165

[2] ATMOSPHERIC MEASUREMENTS OF PYRUVIC AND FORMIC-ACID [J].

ANDREAE, MO ;

TALBOT, RW ;

LI, SM .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1987, 92 (D6) :6635-6641

[3] BIOGENIC HYDROCARBON CONTRIBUTION TO THE AMBIENT AIR OF SELECTED AREAS [J].

ARNTS, RR ;

MEEKS, SA .

ATMOSPHERIC ENVIRONMENT, 1981, 15 (09) :1643-1651

[4] RATE CONSTANTS FOR THE GAS-PHASE REACTIONS OF O-3 WITH THE NATURAL HYDROCARBONS ISOPRENE AND ALPHA-PINENE AND BETA-PINENE [J].

ATKINSON, R ;

WINER, AM ;

PITTS, JN .

ATMOSPHERIC ENVIRONMENT, 1982, 16 (05) :1017-1020

[5] THE OXIDATION OF ISOPRENE IN THE TROPOSPHERE - MECHANISM AND MODEL-CALCULATIONS [J].

BREWER, DA ;

OGLIARUSO, MA ;

AUGUSTSSON, TR ;

LEVINE, JS .

ATMOSPHERIC ENVIRONMENT, 1984, 18 (12) :2723-2744

[6] TERPENOIDS IN THE ATMOSPHERE [J].

GRAEDEL, TE .

REVIEWS OF GEOPHYSICS, 1979, 17 (05) :937-947

[7] NONMETHANE HYDROCARBONS IN REMOTE TROPICAL, CONTINENTAL, AND MARINE ATMOSPHERES [J].

GREENBERG, JP ;

ZIMMERMAN, PR .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1984, 89 (ND3) :4767-4778

[8] HYDROXYL RADICAL OXIDATION OF ISOPRENE [J].

GU, C ;

RYNARD, CM ;

HENDRY, DG ;

MILL, T .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1985, 19 (02) :151-155

[9] PHOTOCHEMISTRY OF BIOGENIC EMISSIONS OVER THE AMAZON FOREST [J].

JACOB, DJ ;

WOFSY, SC .

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1988, 93 (D2) :1477-1486

[10] OZONE-ISOPRENE REACTIONS - PRODUCT FORMATION AND AEROSOL POTENTIAL [J].

KAMENS, RM ;

GERY, MW ;

JEFFRIES, HE ;

JACKSON, M ;

COLE, EI .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1982, 14 (09) :955-975