DIRECT SUBSTITUTION OF SECONDARY ALLYLIC ALCOHOLS WITH O-SILYLATED KETENE ACETALS IN 3.0 M LITHIUM PERCHLORATE-DIETHYL ETHER - AN ALTERNATIVE TO THE [1,3] SIGMATROPIC REARRANGEMENT OF ALLYL VINYL ETHERS

被引：28

作者：

GRIECO, PA

COLLINS, JL

HENRY, KJ

机构：

[1] Department of Chemistry, Indiana University Bloomington

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 33期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)61272-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylic alcohols of type 1 undergo unprecedented substitution with O-silylated ketene acetals in 3.0 M lithium perchlorate-diethyl ether.

引用

收藏

页码：4735 / 4738

页数：4

相关论文

共 5 条

[1] Grieco P.A., 1991, ALDRICHIM ACTA, V24, P59
[2] [1,3] SIGMATROPIC REARRANGEMENT OF ALLYL VINYL ETHERS AT AMBIENT-TEMPERATURE IN 3.0M LITHIUM PERCHLORATE-DIETHYL ETHER
GRIECO, PA
CLARK, JD
JAGOE, CT
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) : 5488 - 5489
[3] DRAMATIC RATE ACCELERATIONS OF DIELS-ALDER REACTIONS IN 5-M LITHIUM PERCHLORATE DIETHYL-ETHER - THE CANTHARIDIN PROBLEM REEXAMINED
GRIECO, PA
NUNES, JJ
GAUL, MD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) : 4595 - 4596
[4] LITHIUM PERCHLORATE CATALYZED CONJUGATE ADDITION OF O-SILYLATED KETENE ACETALS TO HINDERED ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS AT ATMOSPHERIC-PRESSURE
GRIECO, PA
COOKE, RJ
HENRY, KJ
VANDERROEST, JM
[J]. TETRAHEDRON LETTERS, 1991, 32 (36) : 4665 - 4668
[5] CHELATION CONTROLLED ADDITION OF ALLYLSTANNANES TO ALDEHYDES IN LITHIUM PERCHLORATE-DIETHYL ETHER
HENRY, KJ
GRIECO, PA
JAGOE, CT
[J]. TETRAHEDRON LETTERS, 1992, 33 (14) : 1817 - 1820