TETRAALKYLAMMONIUM SALTS IN HECK-TYPE REACTIONS USING AN ALKALI-METAL HYDROGEN CARBONATE OR AN ALKALI-METAL ACETATE AS THE BASE

被引:85
作者
JEFFERY, T
GALLAND, JC
机构
[1] Laboratoire de Synthèse Organique associé au CNRS ENSCP -, 75231 Paris, 11, Rue Pierre et Marie Curie
关键词
D O I
10.1016/S0040-4039(00)73124-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
When used in combination with an alkali metal hydrogen carbonate or an alkali metal acetate, various tetraalkylammonium salts can greatly promote Heck-type reactions, independently of the nature of their anion, provided that the reactions are performed din the presence of molecular sieves. In particular, tetra-n-butylammonium hydrogen sulfate is just as effective as tetra-n-butylammonium chloride under these conditions.
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页码:4103 / 4106
页数:4
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