NITROSYLTRIS(TRIPHENYLPHOSPHINE)RHODIUM AND NITROSYLTRIS(TRIPHENYLPHOSPHINE)COBALT AS NITROSYL TRANSFER REAGENTS

被引：18

作者：

SACCO, A

VASAPOLLO, G

GIANNOCCARO, P

机构：

[1] Istituto di Chimica Generale ed Inorganica, Università di Bari, Bari

来源：

INORGANICA CHIMICA ACTA | 1979年 / 32卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)91656-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Intermolecular transfer of the nitrosyl ligand in RhNOP3 and CoNOP3 to NiCl2P2, CoCIP3CoCl2P2, Co(dpe)2(ClO4)2, FeCl2dpe [P = PPh3;dpe= 1,2-bis-(diphenylhosphino)ethane] readily occurs atroom temperature. On treating RhNOP3 with trityl and silver perchlorate, the cationic species [RhP3)(Me2- CO)]+ and [Rh(NO)2P2]+ have been obtained. IR spectroscopic evidence of the formation of a nitrosyl bridge is cited. © 1979.

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页码：171 / 174

页数：4

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