STEREOSELECTIVE FREE-RADICAL CYCLIZATION ON A SUGAR TEMPLATE THE SULFONYL RADICAL AS A SYNTHETIC TOOL FOR FUNCTIONALIZED GLYCOSIDES

被引：33

作者：

NOUGUIER, R ^{[1
]}

LESUEUR, C ^{[1
]}

DERIGGI, E ^{[1
]}

BERTRAND, MP ^{[1
]}

VIRGILI, A ^{[1
]}

机构：

[1] UNIV AUTONOMA BARCELONA,DEPT QUIM ORGAN,BARCELONA,SPAIN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(00)94437-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of a sulphonyl radical to the external double bond of an allyl glycal generates a pro-chiral carbon radical which adds to the glycal double bond with a high diastereoselectivity. Through three consecutive radical steps, the configurations of three new asymmetric centers are controlled. © 1990.

引用

页码：3541 / 3544

页数：4

共 25 条

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