REDUCTION OF AN ACETYLIDE C=CR TO AN IMINOETHYL GROUP CH2C(R)=NR' IN A BINUCLEAR IRON COMPLEX VIA HYDROGEN MIGRATION FROM NITROGEN TO CARBON - X-RAY STRUCTURE OF FE2(CO)6[CH2C(PH)NME] (PPH2)

被引：20

作者：

CARTY, AJ

MOTT, GN

TAYLOR, NJ

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 04期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0022-328X(00)83950-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Primary amines RNH2 effect reduction of the triple bond of the binuclear σπ-acetylide Fe2(CO)6(CCPh)(PPh2) affording novel iminoethyl complexes Fe2(CO)6{CH2C(Ph)NR}(PPh2) via hydrogen migration from nitrogen to carbon. An X-ray analysis of the iminoalkyl derivative Fe2(CO)6{CH2C(Ph)NMe}(PPh2) shows the reduced ligand bonded as a bridging C(1e)N(2e) donor. © 1979.

引用

页码：C69 / C73

页数：5

共 16 条

[1] ISOCYANIDE INSERTION REACTIONS AND THEIR ROLE IN THE CLUSTER-CATALYZED HYDROGENATION OF ISOCYANIDE MOLECULES
ADAMS, RD
GOLEMBESKI, NM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (10) : 2579 - 2587
[2] STEPWISE REDUCTION OF CARBON-NITROGEN TRIPLE BOND OF ACETONITRILE ON FACE OF A TRI-IRON NONACARBONYL CLUSTER
ANDREWS, MA
KAESZ, HD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (20) : 6763 - 6765
[3] ANDREWS MA, J AM CHEM SOC
[4] AZAM KA, 1977, J CHEM SOC CHEM COMM, P477
[5] NUCLEOPHILIC-ATTACK AT CARBON IN SIGMA, PI-ACETYLIDES - BRIDGING ONE CARBON AND 2 CARBON IMINIUM ION COMPLEXES VIA ADDITION OF CYCLOHEXYLAMINE TO [FE2(CO)6(C2PH)(PPH2)] - X-RAY STRUCTURES OF [FE2(CO)6[CHC(NHC6H11-C)(PH)]PPH2] AND [FE2(CO)6[C(NHC6H11-C)CHPH](PPH2)].0.5C6H6
CARTY, AJ
MOTT, GN
TAYLOR, NJ
YULE, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (10) : 3051 - 3059
[6] METAL PROMOTED ALKYL MIGRATION IN A BIMETALLIC COMPLEX
COLLMAN, JP
ROTHROCK, RK
FINKE, RG
ROSEMUNCH, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (22) : 7381 - 7383
[7] REACTIONS OF DODECACARBONYL-TRIANGULO-TRIOSMIUM WITH ALKENES AND BENZENE - FLUXIONAL BEHAVIOR OF MU3-(ETHAN-1-YL-2-YLIDYNE)-DI-MU-HYDRIDO-TRIANGULO-TRIS(TRICARBONYLOSMIUM) (3OS-OS)
DEEMING, AJ
UNDERHILL, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (13): : 1415 - 1419
[8] REACTIONS OF ACETYLENE, METHYL-SUBSTITUTED AND PHENYL-SUBSTITUTED ACETYLENES, AND ETHYLENE WITH 1,1,1,1,2,2,2,3,3,3-DECACARBONYL-2,3-DI-MU-HYDRIDO-TRI-ANGULO-TRIOSMIUM
DEEMING, AJ
HASSO, S
UNDERHILL, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (15): : 1614 - 1620
[9] GREEN MLH, 1968, ORGANOMETALLIC CHEM, V2
[10] Heck R. F., 1974, ORGANOTRANSITION MET

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