SYNTHESIS AND STRUCTURE OF A HIGH-NUCLEARITY OXOMOLYBDENUM(V) COMPLEX, [(C5ME5RHIII)8(MO(V)12O36)(MO(VI)O4)]2+

被引：49

作者：

CHAE, HK

KLEMPERER, WG

LOYO, DEP

DAY, VW

EBERSPACHER, TA

机构：

[1] UNIV ILLINOIS,DEPT CHEM,URBANA,IL 61801

[2] UNIV ILLINOIS,MAT RES LAB,URBANA,IL 61801

[3] UNIV NEBRASKA,DEPT CHEM,LINCOLN,NE 68588

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 15期

关键词：

D O I：

10.1021/ic00041a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal treatment of MoO3.2H2O with [(C5Me5Rh)2(OH)3]Cl Yields a Cl-/OH- salt of the [(C5Me5Rh)8(Mo13O40)]2+ cation whose metal-oxygen framework is shown on the left. This species contains a central [(MOV12O36)(MOVIO4)]14- core having the [Al13O4(OH)24(H2O)12]7+ framework structure (epsilon-Keggin structure). This dodecanuclear oxomolybdenum (V) complex is comprised of six Mo-Mo dimers and shows for the first time that Mo(V) can form high-nuclearity polyoxoanions.

引用

页码：3187 / 3189

页数：3

共 32 条

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