STEREOSELECTIVE SYNTHESIS OF 7-METHYLHEXADEC-6-ENOIC ACID, A COMPONENT OF CARIBBEAN SPONGE

被引：4

作者：

KULKARNI, BA ^{[1
]}

CHATTOPADHYAY, A ^{[1
]}

MAMDAPUR, VR ^{[1
]}

机构：

[1] BHABHA ATOM RES CTR,DIV BIOORGAN,BOMBAY 400085,INDIA

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 20期

关键词：

D O I：

10.1080/00397919208021115

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The marine natural product (E)-7-methyl hexadec-6-enoic acid(I). has been synthesised for the first time starting from commercially available methyl vinyl ketone. Stereoselective generation of its tri- substituted olefinic moiety is accomplished via Claisen orthoester rearrangement.

引用

页码：2921 / 2925

页数：5

共 7 条

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