ETA-2-DITHIOMETHYLIRON(II) IONIC COMPLEXES - EVIDENCE FOR A STRONG DEPENDENCE ON THE NATURE OF THE TRANS-PHOSPHORUS LIGANDS BONDED TO IRON

被引：11

作者：

TOUCHARD, D ^{[1
]}

LEBOZEC, H ^{[1
]}

DIXNEUF, P ^{[1
]}

机构：

[1] UNIV RENNES,CHIM ORGANOMET LAB,EQUIPE RECH 477,F-35042 RENNES,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 170卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)81093-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cationic η2-dithiomethyliron(II) complexes have been made by alkylation of the uncoordinated sulfur atom of Fe(CO)2[η2-CS2](L)2. Surprisingly, only when the phosphorus ligands L are strong donors (PMe3, PMe2Ph) does coordination of iodide take place to give the neutral Fe(η2-CS2CH3)(I)(CO)(L)2 derivatives. The 13C NMR spectra of the latter at 215 K indicated the presence of both isomers when L was PMe2Ph. Reaction with iodine under carbon monoxide regenerated the cationic precursor. © 1979.

引用

页码：C34 / C36

页数：3

共 4 条

[1] SYNTHESIS OF LOW-VALENT THIOCARBONYL COMPLEXES VIA 1,2-ELIMINATION OF METHYLTHIOL FROM "CIS-METAL-HYDRIDO-DITHIOMETHYLESTER COMPLEXES - OS(CS)(CO)2(PPH3)2 AND IRCL(CS)(PPH3)2
COLLINS, TJ
ROPER, WR
TOWN, KG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 121 (02) : C41 - C44
[2] THIOCARBONYL, H2-DITHIOMETHYL ESTER, AND DITHIOCARBENE COMPLEXES DERIVED FROM CARBON-DISULFIDE COMPLEXES OF RUTHENIUM AND OSMIUM
GRUNDY, KR
HARRIS, RO
ROPER, WR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 90 (02) : C34 - C36
[3] LEBOZEC H, 1978, J CHEM SOC CHEM COMM, P573
[4] LEBOZEC H, 1978, J AM CHEM SOC, V100, P3946

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