C-13 NUCLEAR MAGNETIC-RESONANCE SPECTRA .9. STRAIN EFFECTS ON C-13 CHEMICAL-SHIFTS OF TRIAMANTANE

被引：18

作者：

DHEU, ML

GAGNAIRE, D

DUDDECK, H

HOLLOWOOD, F

MCKERVEY, MA

机构：

[1] RUHR UNIV BOCHUM,CHEM ABT,D-4630 BOCHUM 1,FED REP GER

[2] CNRS,CTR RECH MACROMOLECULES VEGETALES,F-38041 GRENOBLE,FRANCE

[3] NATL UNIV IRELAND UNIV COLL CORK,DEPT CHEM,CORK,IRELAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1979年 / 03期

关键词：

D O I：

10.1039/p29790000357

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 13C n.m.r. spectrum of triamantane (3) observed at 22.64 and 62.8 MHz is assigned using selective 1H decoupling. Internal strain causing geometrical distortions at the quaternary carbon leads to a non-additive downfield shift of its signal.

引用

页码：357 / 359

页数：3

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