MUTUAL DIFFUSION IN DENSE SUPERCRITICAL FLUIDS

被引:9
作者
MCCONALOGUE, DJ
MCLAUGHLIN, E
机构
[1] Centre for Computing and Automation, Imperial College, London
[2] Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA
[3] Department of Chemical Engineering and Chemical Technology, Imperial College, London
基金
美国国家科学基金会;
关键词
D O I
10.1080/00268976900100541
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An expression for the mutual diffusion coefficient of a dense binary system of hard spheres, derived by using the Percus-Yevick approximation for the contact radial distribution function, together with Thorne's extension of the Enskog theory, is used to study the variation of the mutual diffusion coefficient with pressure, composition and ratio of the molecular diameters. Applications are made to real systems. © 1969 Taylor and Francis Group, LLC.
引用
收藏
页码:501 / +
页数:1
相关论文
共 12 条
[1]   DIFFUSION COEFFICIENTS OF THE SYSTEMS CO2-CO2 AND CO2-N2O [J].
AMDUR, I ;
IRVINE, JW ;
MASON, EA ;
ROSS, J .
JOURNAL OF CHEMICAL PHYSICS, 1952, 20 (03) :436-443
[2]  
CHAPMAN S, 1953, MATHEMATICAL THEORY, P273
[3]   DIFFUSION OF KRYPTON-85 IN DENSE GASES [J].
DURBIN, L ;
KOBAYASHI, R .
JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (08) :1643-&
[4]   DIFFUSION IN CO2-CH4 MIXTURES TO 225 ATMOSPHERES PRESSURE [J].
JEFFRIES, QR ;
DRICKAMER, HG .
JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (03) :436-437
[5]   THERMODYNAMIC PROPERTIES OF MIXTURES OF HARD SPHERES [J].
LEBOWITZ, JL ;
ROWLINSON, JS .
JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (01) :133-&
[6]  
LEBOWITZ JL, 1964, PHYS REV A, V133, P895, DOI DOI 10.1103/PHYSREV.133.A895
[7]  
LONGUETHIGGINS HC, 1958, TRANSPORT PROCESSES, P73
[8]  
MCLAUGHLIN E, IN PRESS
[9]   Phase equilibria in hydrocarbon systems - Methane-carbon dioxide system in the gaseous region [J].
Reamer, HH ;
Olds, RH ;
Sage, BH ;
Lacey, WN .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1944, 36 :88-90
[10]   EQUATION OF STATE OF DENSE SYSTEMS [J].
ROWLINSON, JS .
REPORTS ON PROGRESS IN PHYSICS, 1965, 28 :169-+