SIMPLE BOND RUPTURE REACTIONS IN MULTI-PHOTON DISSOCIATION OF MOLECULES

被引:196
作者
SUDBO, AS [1 ]
SCHULZ, PA [1 ]
GRANT, ER [1 ]
SHEN, YR [1 ]
LEE, YT [1 ]
机构
[1] UNIV CALIF BERKELEY,DEPT MANAGEMENT SCI,BERKELEY,CA 94720
关键词
D O I
10.1063/1.437482
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A molecular beam study was carried out of the infrared multiphoton dissociation of seven molecules dissociating by a simple bond rupture. Translational energy distributions for the dissociation products were obtained, and the results can be described very well by a statistical (RRKM) theory of unimolecular reactions. A general discussion of the main features of the multiphoton dissociation process is given. © 1979 American Institute of Physics.
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收藏
页码:912 / 929
页数:18
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