ABSORPTION OF MONODEUTEROMETHANE (CH3D)-C-12 AT 4.5 MU-M, ANALYSIS OF THE OVERTONE BAND 2-NU-6

被引：14

作者：

POUSSIGUE, G ^{[1
]}

TARRAGO, G ^{[1
]}

CARDINET, P ^{[1
]}

VALENTIN, A ^{[1
]}

机构：

[1] UNIV PARIS 06, SPECTRON MOLEC LAB, F-75234 PARIS 05, FRANCE

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1980年 / 82卷 / 01期

关键词：

Molecular physics - Physical chemistry;

D O I：

10.1016/0022-2852(80)90098-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The overtone band 2ν6 of 12CH3D is analyzed in the range 2088-2433 cm-1. The parallel and perpendicular components, centered at 2316.266 and 2323.297 cm-1, are strongly interacting, giving rise to a number of forbidden transitions and large A1A2 splittings. Six hundred twelve transitions including J′ values up to 13 are assigned; the vibration-rotation constants for the upper state u6 = 2 are derived from these data, allowing the reproduction of the experimental wavenumbers with a rms equal to 0.007 cm-1. Some intensity measurements are used to estimate the overall band strength of 2ν6. Copyright © 1980 by Academic Press, Inc.

引用

页码：35 / 53

页数：19

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