MEASUREMENT OF LIMITING ACTIVITY-COEFFICIENTS FOR AQUEOUS SYSTEMS BY DIFFERENTIAL EBULLIOMETRY

被引：40

作者：

BERGMANN, DL

ECKERT, CA

机构：

[1] GEORGIA TECH,SCH CHEM ENGN,ATLANTA,GA 30332

[2] UNIV ILLINOIS,DEPT CHEM ENGN,URBANA,IL 61801

来源：

FLUID PHASE EQUILIBRIA | 1991年 / 63卷 / 1-2期

关键词：

D O I：

10.1016/0378-3812(91)80026-R

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

New data have been determined by differential ebulliometry for limiting activity coefficients of binary systems of water. Results are reported with acetone, N,N-dimethylformamide, ethyl acetate, isopropanol, methanol, nitromethane and tetrahydrofuran over a modest range of temperatures. The results are used to demonstrate the limitations of several current excess Gibbs energy expressions in representing both vapour-liquid equilibrium and liquid-liquid equilibrium data from limiting activity coefficient measurements.

引用

页码：141 / 150

页数：10

共 15 条

[1]

BERGMANN DL, 1990, THESIS U ILLINOIS UR

[2] ACTIVITY COEFFICIENTS AT INFINITE DILUTION [J].