PALLADIUM(II) PROMOTED O-GLYCOSYLATION INVOLVING 1-THIO-2-ENOSIDES AND 3-THIO-1-ENOSES

被引：19

作者：

TAKEDA, K

NAKAMURA, H

AYABE, A

AKIYAMA, A

HARIGAYA, Y

MIZUNO, Y

机构：

[1] School of Pharmaceutical Sciences, Kitasato University, Minato-ku, Tokyo, 108, Shirokane

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 01期

关键词：

D O I：

10.1016/0040-4039(94)88180-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

O-glycosylation of thioglycosyl donors, 2,3-dideoxy-hex-1-thio-2-enopyranosides, 1,2-dideoxy-hex-3-thio-1-nopyranoses ad 2-pyridyl 2,3,4,6-tetra-O-benzyl-1-thio-beta-D-glucopyranoside was achieved by use of a Pd(II) activator which was prepared from bis(acetonitrile)dichloropalladium(II)(Pd(CH3CN)(2)Cl-2) and silver triflate (AgOTf).

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页码：125 / 128

页数：4

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