DIRECT TRANSFORMATION OF TRIALKYL PHOSPHATES INTO ORGANOLITHIUM COMPOUNDS BY A DTBB-CATALYZED LITHIATION

被引：34

作者：

GUIJARRO, D ^{[1
]}

MANCHENO, B ^{[1
]}

YUS, M ^{[1
]}

机构：

[1] UNIV ALICANTE,FAC CIENCIAS,DEPT QUIM ORGAN,E-03080 ALACANT,SPAIN

来源：

TETRAHEDRON | 1994年 / 50卷 / 28期

关键词：

D O I：

10.1016/S0040-4020(01)85573-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of different alkylic or phenylic phosphates 1 with an excess of lithium powder and a catalytic amount of DTBB (5 mol %) in the presence of an electrophile -Barbier-type reaction conditions- in THF at -30 degrees C leads to the formation of the expected products 2, resulting from the reaction of the in situ generated organolithium compound with the corresponding electrophile.

引用

页码：8551 / 8558

页数：8

共 45 条

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