INTRAMOLECULAR CYCLIZATIONS OF ALPHA-STANNYL RADICALS TO ACYLSILANES - REGIOSPECIFIC SYNTHESES OF 5-MEMBERED CYCLIC SILYL ENOL ETHERS

被引：25

作者：

TSAI, YM

CHANG, SY

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 09期

关键词：

D O I：

10.1039/c39950000981

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

alpha-Stannyl radicals generated from acylsilanes 5, 13 and 14 cyclize to give good yields of cyclic silyl enol ethers after sequential cyclizations, radical Brook rearrangements and beta-scissions.

引用

页码：981 / 982

页数：2

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