PHASE ANALYSES OF LANTHANIDE OXIDE FLUORIDES

被引：46

作者：

SHINN, DB

EICK, HA

机构：

[1] Department of Chemistry, Michigan State University, East Lansing

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 02期

关键词：

D O I：

10.1021/ic50072a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Approximate composition limits and lattice parameters of the rhombohedral and tetragonal phases observed in the system LnO1-xF1+2x (Ln = Nd, Gd, Er) are reported. Variation of the cia ratio of the tetragonal phase with atomic number is noted and discussed. The rhombohedral to cubic transition temperatures of LnO1-xF1+2x (Ln = La, Nd, Sin, Eu, Gd, Tb, Dy, Y, Ho, and Er) determined from differential thermal analysis are reported and the transition is discussed. Thermal expansion data are reported for NdOF and its mode of thermal decomposition is indicated. © 1969, American Chemical Society. All rights reserved.

引用

页码：232 / &

共 21 条

[1] UNIT CELL DIMENSIONS OF SOME RARE EARTH OXYFLUORIDES [J].

BAENZIGER, NC ;

HOLDEN, JR ;

KNUDSON, GE ;

POPOV, AI .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (18) :4734-4735

[2]

BATSANOVA LR, 1964, RUSS J INORG CHEM, V9, P181

[3]

Bevan D.J.M., 1968, INORG NUCL CHEM LETT, V4, P241

[4]

CAMPBELL WJ, 1962, 8107 US BUR MIN INF

[5] YTTRIUMOXYFLUORID [J].

HUND, F .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1951, 265 (1-3) :62-66

[6] STORUNGSMESSUNG AM METASTABILEN BETA-YOF [J].

HUND, F .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1953, 273 (06) :312-318

[7]

Klemm W, 1941, Z ANORG ALLG CHEM, V248, P167

[8]

MAZZA L, 1951, ATTI ACCAD LIGURE SC, V7, P44

[9]

PODBEREZSKAYA NV, 1965, J STRUCT CHEM, V6, P815

[10] PREPARATION AND PROPERTIES OF THE RARE EARTH FLUORIDES AND OXYFLUORIDES [J].

POPOV, AI ;

KNUDSON, GE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (15) :3921-3922

← 1 2 3 →