AN UNUSUALLY LOW EXO-ENDO RATE RATIO IN SOLVOLYSIS OF 2,7,7-TRIMETHYL-2-NORBORNYL P-NITROBENZOATES . EVIDENCE FOR STERIC EFFECTS AS A MAJOR FACTOR IN EXO-ENDO RATE AND PRODUCT RATIOS OF NORBORNYL DERIVATIVES

被引：38

作者：

BROWN, HC

IKEGAMI, S

机构：

[1] Richard B. Wetherill Laboratory Purdue University, Lafayette

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1968年 / 90卷 / 25期

关键词：

D O I：

10.1021/ja01027a043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：7122 / &

共 14 条

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[3] RATES OF REACTION OF SODIUM BOROHYDRIDE WITH BICYCLIC KETONES STERIC APPROACH CONTROL AND STERIC DEPARTURE CONTROL IN REACTIONS OF RIGID BICYCLIC SYSTEMS
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[4] RATES OF SOLVOLYSIS OF RHO-NITROBENZOATES OF EXO-ENDO TERTIARY NORBORNEOLS . CRITICAL EXAMINATION OF EXO-ENDO RATE RATIO AS BASIS FOR POSTULATED NONCLASSICAL STRUCTURE OF NORBORNYL CATION
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[5] GOERING-SCHEWENE DIAGRAM FOR 1,2-DIMETHYLNORBORNYL SYSTEM . A REMARKABLE SIMILARITY IN DIAGRAMS FOR CLASSICAL TERTIARY NORBORNYL CATIONS AND SECONDARY NORBORNYL SPECIES
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[6] APOISOBORNYL-EXO-CAMPHENILYL NONCLASSICAL CATION
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[7] SOLVOLYSIS OF OPTICALLY ACTIVE 1,2-DIMETHYL-EXO-2-NORBORNYL P-NITROBENZOATE . EVIDENCE FOR INVOLVEMENT OF A CLASSICAL CARBONIUM ION
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[9] HUCKEL W, 1963, ANN CHEM, V664, P31
[10] AN UNUSUALLY HIGH EXO-ENDO RATE RATIO IN SOLVOLYSIS OF 2,6,6-TRIMETHYL-2-NORBORNYL P-NITROBENZOATES . FURTHER EVIDENCE FOR STERIC EFFECTS AS A MAJOR FACTOR IN EXO-ENDO RATE RATIOS OF NORBORNYL DERIVATIVES
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (25) : 7124 - &

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