ESR EVIDENCE FOR HALOGEN OXY-RADICAL FORMATION IN THE STUDY OF THE HETEROGENEOUS DECOMPOSITION OF GASEOUS-HYDROGEN PEROXIDE ON HALIDES

被引：11

作者：

CARLIER, M

SAHETCHIAN, K

SOCHET, LR

机构：

[1] Laboratoire de Cinétique et Chimie de la Combustion, Université de Sciences et Techniques de Lille

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80338-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Above 200°C, the reaction of H2O2 on walls coated with halides (e.g. KCl, KBr) leads not only to HO-2 from H2O2 decomposition but also to the formation of halide dioxides from the coating. The possible influence of halogenated compounds eventually formed during hydrocarbon oxidation carried out in halide-coated vessels is suggested. © 1979.

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页码：557 / 560

页数：4

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