A FACILE SYNTHESIS OF [(FE(SALPHEN))2O] (SALPHENH2 = N,N'-O-PHENYLENEBIS(SALICYLIDINEIMINE)) AND THE X-RAY CRYSTAL-STRUCTURE OF [(FE(SALPHEN))2O].DMSO

被引：31

作者：

ASHMAWY, FM ^{[1
]}

UJAIMI, AR ^{[1
]}

MCAULIFFE, CA ^{[1
]}

PARISH, RVD ^{[1
]}

PRITCHARD, RG ^{[1
]}

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

来源：

INORGANICA CHIMICA ACTA | 1991年 / 187卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)90388-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of ferric perchlorate with the disodium salt of N,N'-omicron-phenylenebis(salicylideneimine) in ethanol produces the mu-oxo complex [{Fe(salphen)}2O]. Recrystallization from dimethyl sulfoxide produces dark red [{Fe(salen)}2O].DMSO which single crystal X-ray studies show to be a square-based pyramid linked by Fe-O bonds; Fe-O 1.776(7) and 1.781(7) angstrom, Fe-O-Fe 146.7(4)-degrees.

引用

页码：155 / 158

页数：4

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