STRICT SELF-ASSEMBLY OF [FE(CYCLAM)](3+) AND [HYDROGEN-BIS-(1,1'-FERROCENEDICARBOXYLATE)](3-) INTO A NOVEL MIXED-VALENT ONE-DIMENSIONAL POLYMER CONTAINING AN FE(III)N4O2 CHROMOPHORE

被引：30

作者：

CHRISTIE, SD

SUBRAMANIAN, S

THOMPSON, LK

ZAWOROTKO, MJ

机构：

[1] ST MARYS UNIV,DEPT CHEM,HALIFAX B3H 3C3,NS,CANADA

[2] MEM UNIV NEWFOUNDLAND,DEPT CHEM,ST JOHNS A1B 3X7,NF,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 22期

关键词：

D O I：

10.1039/c39940002563

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

trans-[Fel(III)(cyclam)][(FC(CO2)2)(2)H], 1, (cyclam = 1,4,8,1 1-tetraazacyclotetradecane; [FC(CO2)(2)](2-) = 1,1'-ferrocenedicarboxylate) strictly self-assembles via Fe-III-carboxylate covalent bonds and hydrogenbiscarboxylate hydrogen bonds to form a one-dimensional polymer that contains the first crystallographically characterized (FeN4O2)-N-III chromopore.

引用

收藏

页码：2563 / 2564

页数：2

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