SIDE-BONDED KETONE COMPLEXES OF PLATINUM(O) - ALLOXAN AND DIETHYL OXOMALONATE COMPLEXES AND REACTIONS OF PLATINUM(O) COMPLEXES WITH ISATIN AND BENZOYL CYANIDE

被引：31

作者：

CLARKE, DA ^{[1
]}

HUNT, MM ^{[1
]}

KEMMITT, RDW ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 175卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)84551-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of alloxan (all) with [PtL(PPh3)2] (L′= trans-stilbene, L″ diphenylacetylene) afford the side-bonded ketone complex [Pt(all)(PPh3)2] which may also be obtained from the hydrate of alloxan and [PtL′(Pph3)2]. Similarly diethyl oxomalonate (dio) and [Pt(PPh3)4] afford a side-bonded ketone complex [Pt(dio)(PPh3)2]. Reaction of isatin with [Pt(PPh34] gives trans-[PtH{NCO(o-C6H4)CO}(PPh3)2] and benzoyl cyanide and [PtL′(PPh3)2] give cis-[Pt(CN)(COPh3)2] and trans-[Pt(CN)2(PPh2)2]. © 1979.

引用

页码：303 / 313

页数：11

共 25 条

[1]

ALLEN AD, 1964, CANAD J CHEM, V4, P1063

[2] METAL COMPLEXES CYANOCARBONS .10. PHOTOCHEMICAL ISOMERIZATION OF A DICYANOACETYLENE COMPLEX OF PLATINUM AND STRUCTURE OF CYANO-(CYANOACETYLIDO)BIS(TRIPHENYLPHOSPHINE)PLATINUM(II) [J].