LASER-COLLISION INDUCED CHEMICAL-REACTIONS - COLLINEAR EXCHANGE-REACTION MODEL ON 2 ELECTRONIC SURFACES

被引：57

作者：

LIGHT, JC

ALTENBERGERSICZEK, A

机构：

[1] UNIV CHICAGO,DEPT CHEM,CHICAGO,IL 60637

[2] ARGONNE NATL LAB,DIV CHEM ENGN,ARGONNE,IL 60439

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 09期

关键词：

D O I：

10.1063/1.438035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A collinear model of bimolecular exchange reactions in the presence of an intense laser field coupling two electronic potential energy surfaces is developed. Close coupling calculations for two model systems were carried out as a function of the initial energy, E, the laser coupling, μE0, and the laser frequency, ℏω. It is shown that the reaction probability can be greatly altered for some systems by intense off-resonant laser radiation. A suggestion is made for laser frequency up-conversion using exothermic chemical reactions. © 1979 American Institute of Physics.

引用

页码：4108 / 4116

页数：9

共 33 条

[1] QUANTUM-MECHANICAL THEORY OF COLLISIONAL IONIZATION IN PRESENCE OF INTENSE LASER-RADIATION [J].