Simulataneous pair electronic excitations in a binuclear iron(III) complex

被引：42

作者：

Schugar, Harvey J. ^{[1
]}

Rossman, George R. ^{[2
]}

Thibeault, Jack ^{[2
]}

Gray, Harry B. ^{[2
]}

机构：

[1] Rutgers State Univ, Dept Chem, New Brunswick, NJ 08903 USA

[2] CALTECH, Arthur Amos Noyes Lab Chem Phys, Pasadena, CA 91109 USA

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 01期

关键词：

D O I：

10.1016/0009-2614(70)80066-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ultraviolet absorption spectrum of an isolated metal complex containing the bridging unit Fe(III)...O-Fe(III) shows several bands due to the simultaneous electronic excitation of the two Fe( III) center. The band positiors are in excellent agreement with calculated sums of one-center d-d transitions.

引用

页码：26 / 28

页数：3

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