SYNTHETIC APPROACHES TO [N](3,5)-TROPONOPHANES - NOVEL REARRANGEMENTS OF 10,10-DICHLORO-1,2,6,7,8,9-HEXAHYDRO-4A,9A-METHANO-5H-BENZOCYCLOHEPTEN-2-ONE

被引：4

作者：

BANWELL, MG ^{[1
]}

GABLE, RW ^{[1
]}

RYAN, JH ^{[1
]}

MACKAY, MF ^{[1
]}

机构：

[1] LA TROBE UNIV,DEPT CHEM,BUNDOORA,VIC 3083,AUSTRALIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 08期

关键词：

D O I：

10.1039/c39940001015

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On standing the title compound 1c gives an enone isomer 4 and the heptacyclic compound 5; the formation of both of these products has been rationalised in terms of the intermediacy of the bridged tropylium ion 8 and C-13-labelling studies support this proposal.

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页码：1015 / 1017

页数：3

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