PREPARATION AND PROPERTIES OF PENTAFLUOROSULFANYLDICHLORAMINE SF5NCL2

被引：19

作者：

CLIFFORD, AF

ZEILENGA, GR

机构：

[1] Department of Chemistry, Purdue University, West Lafayette, Indiana

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 04期

关键词：

D O I：

10.1021/ic50074a052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of NSF3 and C1F yields pentafluorosulfanyldichloramine, SF5NCl2. The compound is a light yellow liquid with a boiling point of 64° and a melting point of -120°. It is sensitive to mechanical shock and is thermally unstable at 80°. Hydrolysis and the reaction of SF5NCl2 with mercury were slow. © 1969, American Chemical Society. All rights reserved.

引用

页码：979 / &

共 9 条

[1] PREPARATION AND PROPERTIES OF PENTAFLUOROSULFANYLIMINOSULFUR DIFLUORIDE SF5N=SF2
CLIFFORD, AF
THOMPSON, JW
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[2] CLIFFORD AF, 1965, INORG CHEM, V4, P511
[3] CLIFFORD AF, 1966, INORG CHEM, V5, P692
[4] THE INFRA-RED SPECTRA OF SOME DERIVATIVES OF SULPHUR HEXAFLUORIDE
CROSS, LH
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[5] EMSLEY JW, 1964, HIGH RESOLUTION NUCL, P931
[6] ADDITION OF CHLORINE MONOFLUORIDE TO FLUORINATED NITRILES
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[J]. INORGANIC CHEMISTRY, 1966, 5 (03) : 488 - &
[7] HIGH-RESOLUTION NUCLEAR MAGNETIC RESONANCE SPECTRA OF PENTAFLUOROSULFUR GROUP
MERRILL, CI
CADY, GH
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WILLIAMSON, SM
[J]. INORGANIC CHEMISTRY, 1962, 1 (02) : 215 - &
[8] THE INFRARED SPECTRA AND STRUCTURE OF THE CHLORAMINES AND NITROGEN TRICHLORIDE
MOORE, GE
BADGER, RM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (23) : 6076 - 6080
[9] SYNTHESIS + CHEMISTRY OF SF5CL
TULLOCK, CW
COFFMAN, DD
MUETTERTIES, EL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (03) : 357 - &

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