ETHYLENE DISPLACEMENT-REACTIONS OF H5-INDENYLBIS-(ETHYLENE)RHODIUM(I)

被引：44

作者：

ESHTIAGHHOSSEINI, H

NIXON, JF

机构：

[1] School of Molecular Sciences, University of Sussex, Brighton

来源：

JOURNAL OF THE LESS-COMMON METALS | 1978年 / 61卷 / 01期

关键词：

D O I：

10.1016/0022-5088(78)90151-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The barrier to ethylene rotation in h5-indenylbis(ethylene)rhodium I is lower than that in the analogous h5-cyclopentadienyl complex and ethylene is readily displaced by carbon monoxide, fluorophosphines and also by more basic phosphines to form Rh(h5-C9H7)L2 complexes. Unhindered dienes also displace ethylene from I. Several mixed ligand complexes of the type Rh(h5-C9H7)LL′ (L = phosphine or CO) are also reported and possible mechanisms of ethylene displacement are discussed. © 1978.

引用

页码：107 / 121

页数：15

共 26 条

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