TE-8(2+), A NEW TELLURIUM POLYCATION

被引：36

作者：

BECK, J

机构：

[1] Institut für Anorganische Chemie, Universität Karlsruhe, D-7500, Engesserstrasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 03期

关键词：

D O I：

10.1002/anie.199002931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Te8[WCl6]2 is formed upon oxidation of tellurium with WCl6. In the crystal the bicyclic Te 82⊕ cation is associated to give chains (see 1) and can be regarded as a tellurium polycation [Ten]n/4⊕ Such polycations were already postulated almost 20 years ago by R. J. Gillespie, but up to now they have never been structurally characterized. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

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页码：293 / 295

页数：3

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