IODINE OXIDATIVE COUPLING OF DIENE AND TRIENE-DIOLATES OF UNSATURATED CARBOXYLIC-ACIDS

被引：6

作者：

AURELL, MJ ^{[1
]}

GIL, S ^{[1
]}

PARRA, M ^{[1
]}

TORTAJADA, A ^{[1
]}

MESTRES, R ^{[1
]}

机构：

[1] UNIV VALENCIA,DEPT QUIM ORGAN,VALENCIA,SPAIN

来源：

TETRAHEDRON | 1991年 / 47卷 / 10-11期

关键词：

D O I：

10.1016/S0040-4020(01)96111-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidative Coupling of the dianions of unsaturated carboxylic acids 1, and 4 with iodine, which provides a convenient and facile preparation of gamma,gamma and epsilon,epsilon-dicarboxylic acids 2 and 5, apparently occurs through SET substitution of intermediate iodo-carboxylates.

引用

页码：1997 / 2004

页数：8

共 9 条

[1] AURELL MJ, 1990, SYNTHESIS-STUTTGART, P317
[2] SILVER ION OXIDATIVE COUPLING OF DIENE AND TRIENE-DIOLATES OF UNSATURATED CARBOXYLIC-ACIDS - A FACILE SYNTHESIS OF OCTA-DIENEDIOIC AND DODECA-DIENEDIOIC ACIDS
AURELL, MJ
GIL, S
TORTAJADA, A
MESTRES, R
GARCIARASO, A
[J]. TETRAHEDRON LETTERS, 1988, 29 (47) : 6181 - 6182
[3] BALLESTER P, 1985, SYNTHESIS-STUTTGART, P802
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[5] SYNTHESIS OF UNSATURATED 5-HYDROXY-ACIDS AND 7-OXO-ACIDS BY ADDITION OF UNSATURATED CARBOXYLIC-ACID DIENOLATES TO CARBONYL-COMPOUNDS
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[6] CONDENSATION OF CROTONIC AND TIGLIC ACID DIANIONS WITH ALDEHYDES AND KETONES
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WHITE, JD
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (23) : 4424 - 4429
[7] DIENEDIOLATES FROM UNSATURATED CARBOXYLIC-ACIDS - REACTION WITH PARA-SUBSTITUTED BENZALDEHYDES - ELECTRONIC EFFECTS ON REGIOSELECTIVITY
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MESTRES, R
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (02): : 327 - 332
[8] AN ELECTROCHEMICAL CHARACTERIZATION OF DIANIONS - DILITHIATED CARBOXYLIC-ACIDS
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FOX, MA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (17) : 5705 - 5709
[9] REACTION OF DILITHIATED CARBOXYLIC-ACIDS WITH IODINE - EVIDENCE FOR THE FORMATION OF A RADICAL-ANION INTERMEDIATE
RENAUD, P
FOX, MA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (16) : 3745 - 3752

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