FINE-STRUCTURE IN THE INNER VALENCE PHOTOELECTRON-SPECTRA OF N2 AND CO

被引：41

作者：

LIU, ZF

BANCROFT, GM

COATSWORTH, LL

TAN, KH

机构：

[1] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON N6A 5B7,ONTARIO,CANADA

[2] UNIV WESTERN ONTARIO,CANADIAN INST SYNCHROTRON RADIAT,LONDON N6A 5B7,ONTARIO,CANADA

[3] UNIV WISCONSIN,SYNCHROTRON RADIAT CTR,CANADIAN SYNCHROTRON RADIAT FAC,STOUGHTON,WI 53589

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 203卷 / 04期

关键词：

D O I：

10.1016/0009-2614(93)85578-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The high-resolution (almost-equal-to 0.1 eV) inner valence photoelectron spectra of N2 and CO, with the binding energy in the 29-42 eV region are reported. For the first time, the effects of vibronic coupling are clearly resolved. Both spectra exhibit great complexity in structure. A preliminary assignment, based on calculations which only considered the electronic excitations, is given.

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页码：337 / 343

页数：7

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