EFFECT OF A HOMOALLYLIC DOUBLE-BOND ON RATES OF SOLVOLYSIS OF 1-PHENYCYCLOPENTYL AND 2-PHENYL-2-NORBORNANYL PARA NITROBENZOATES - EVIDENCE FOR ABSENCE OF PI PARTICIPATION AS A FACTOR IN HIGH EXO - ENDO RATE RATIO IN 2-PHENYL-2-NORBORNENYL SYSTEM

被引：9

作者：

PETERS, EN

BROWN, HC

机构：

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1972年 / 94卷 / 22期

关键词：

D O I：

10.1021/ja00777a042

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：7920 / &

共 19 条

[1]

BARTLETT PD, 1963, J ORG CHEM, V28, P3351

[2] STEREOCHEMISTRY OF METHYLENE TRANSFER FROM SULFONIUM YLIDES TO UNSATURATED BICYCLIC KETONES [J].

BLY, RS ;

DUBOSE, CM ;

KONIZER, GB .

JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (06) :2188-&

[3] RATES OF REACTION OF SODIUM BOROHYDRIDE WITH BICYCLIC KETONES STERIC APPROACH CONTROL AND STERIC DEPARTURE CONTROL IN REACTIONS OF RIGID BICYCLIC SYSTEMS [J].

BROWN, HC ;

MUZZIO, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (12) :2811-+

[4] RATES OF SOLVOLYSIS OF RHO-NITROBENZOATES OF EXO-ENDO TERTIARY NORBORNEOLS . CRITICAL EXAMINATION OF EXO-ENDO RATE RATIO AS BASIS FOR POSTULATED NONCLASSICAL STRUCTURE OF NORBORNYL CATION [J].

BROWN, HC ;

CHLOUPEK, FJ ;

REI, MH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (06) :1248-+

[5]

BROWN HC, BORANES ORGANIC CHEM, pCH9

[6]

BROWN HC, BORANES ORGANIC CHEM, pCH10

[7]

BROWN HC, BORANES ORGANIC CHEM, pCH11

[8]

Bunton C A., 1963, Nucleophilic Substitution at a Saturated Carbon Atom

[9]

BUNTON CA, 1965, CHEM IND-LONDON, P1182

[10] PROTON NUCLEAR MAGNETIC RESONANCE ANALYSIS OF STABLE CLASSICAL 2-PHENYL-2-NORBORNYL AND RELATED CATIONS [J].

FARNUM, DG ;

MEHTA, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (12) :3256-&

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