A GENERAL SYNTHETIC ROUTE TO HIGH-MOLECULAR-WEIGHT POLY(P-XYLYLENE)-DERIVATIVES - A NEW ROUTE TO POLY(P-PHENYLENE VINYLENE)

被引:60
作者
LOUWET, F
VANDERZANDE, D
GELAN, J
机构
[1] Laboratorium for Organic Chemistry, Limburg University, Institute for Material Research, Universitaire Campus
关键词
D O I
10.1016/0379-6779(94)02548-D
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new synthetic route to high molecular weight poly(p-xylylene)-derivatives 4 has been investigated. If the substituents on the ethylene segment could be eliminated (4a-b) this method provides a new route to PPV from a precursor polymer that is amenable to conventional non-aqueous processing techniques. The effect of basic reagents on the high molecular weight 4 has been explained as a degradation mechanism.
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页码:509 / 510
页数:2
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