CYCLOPROPANE AMINO ACIDS FROM AESCULUS AND BLIGHIA

被引：82

作者：

FOWDEN, L

SMITH, A

机构：

来源：

PHYTOCHEMISTRY | 1969年 / 8卷 / 02期

关键词：

D O I：

10.1016/S0031-9422(00)85446-1

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

070307 [化学生物学]; 071010 [生物化学与分子生物学];

摘要：

Three compounds containing cyclopropane ring systems have been newly characterized from Aesculus parviflora and Blighia sapida. Exo-3,4-methanoproline was isolated together with its probable biogenetic precursor, cis-α-(carboxycyclopropyl)glycine, from seeds of Aesculus, whilst the structurally related trans-α-(carboxycyclopropyl)glycine was obtained from Blighia seed. The structures were assigned following the analysis of the hydrogenation products obtained from each substance and of the NMR and mass spectra of the compounds. © 1969.

引用

页码：437 / &

共 10 条

[1]

ALLENES .19. SYNTHESIS OF (+-)-HYPOGLYCIN A AND CONFIGURATION OF NATURAL ISOMER [J].