SIGMA,SIGMA'-N,N' BRIDGING AND SIGMA,SIGMA-N,N CHELATING ALPHA-DIIMINES - MOLECULAR GEOMETRIES OF [PTCL2PBU3]2(T-BUN=CHCH=NBU-T) AND PTCL2(STYRENE)-(T-BUN=CHCH=NBU-T)

被引：48

作者：

VANDERPOEL, H

VANKOTEN, G

VRIEZE, K

KOKKES, M

STAM, CH

机构：

[1] UNIV AMSTERDAM,JH VANTHOFF INST,ANORGAN CHEM LAB,NL-1018 WV AMSTERDAM,NETHERLANDS

[2] UNIV AMSTERDAM,JH VANTHOFF INST,KRISTALLOG LAB,AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 175卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)84555-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

X-ray structure analysis of [PtCl2PBu3]2(t-BuNCHCHNBu-t) has shown the presence of σ,σ′-N,N′-bonded diimine, which bridges in the anticonfiguration two planar trans-PtCl2PBu3N moieties. The crystal structure of PtCl2(styrene)(t-BuNCHCHNBu-t) contains a unidentate-bonded styrene molecule in the equatorial position of a trigonal bipyramidal arrangement with the phenyl ring bent back by 27°. © 1979.

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页码：C21 / C24

页数：4

相关论文

共 11 条

[1] BONDING PROPERTIES OF MO(CO)4-XL(PR3)X (X=0,1,2-L=DIAZABUTADIENE, PYRIDINE-2-CARBALDEHYDE IMINE AND 2,2'-BIPYRIDINE) - INFRARED, ELECTRONIC ABSORPTION, H-1, C-13 AND P-31 NMR AND RESONANCE RAMAN-SPECTRA [J].

BALK, RW ;

STUFKENS, DJ ;

OSKAM, A .

INORGANICA CHIMICA ACTA, 1978, 28 (01) :133-143

[2]

Graham A. J., 1977, CRYST STRUCT COMMUN, V6, P571

[3]

GRAHAM AJ, 1977, CRYST STRUCT COMMUN, V6, P253

[4] MOLECULAR-STRUCTURE OF N,N'-DI-TERT-BUTYL-1,2-ETHANEDIIMINE, (CH3)3CN=CHCH=NC(CH3)3, AS STUDIED BY GAS ELECTRON-DIFFRACTION [J].

HARGITTAI, I ;

SEIP, R .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1976, 30 (07) :540-546

[5]

KLERKS JM, UNPUBLISHED

[6] 5-CO-ORDINATE ETHYLENE COMPLEXES OF PLATINUM(II) .2. SYNTHESIS AND REACTIVITY OF SOME 5-CO-ORDINATE COMPLEXES OF PLATINUM WITH BIS(HYDRAZONES) AND X-RAY CRYSTAL-STRUCTURE OF [BUTANE-2,3-DIONE BIS(METHYLHYDRAZONE)]DICHLORO(ETA-ETHYLENE)PLATINUM(II) [J].

MARESCA, L ;

NATILE, G ;

CALLIGARIS, M ;

DELISE, P ;

RANDACCIO, L .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (22) :2386-2390

[7] ALKENYLARYL COMPOUNDS OF NICKEL(II) AND PALLADIUM(II) - INFLUENCE OF TRANSITION METAL ON LIGAND PROTON CHEMICAL SHIFTS [J].

MILLER, RG ;

STAUFFER, RD ;

FAHEY, DR ;

PARNELL, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (06) :1511-&

[8] EVIDENCE FOR AN OSCILLATING INTRAMOLECULAR LIGAND-EXCHANGE MECHANISM DUE TO AN ALTERNATION BETWEEN 2 IDENTICALLY STRONG ALIPHATIC HYDROGEN TO PALLADIUM INTERACTIONS [J].

POSTEL, M ;

PFEFFER, M ;

RIESS, JG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (17) :5623-5627

[9] STUDY OF ELECTRONIC PROPERTIES OF M(CO)4DAB (M=CR,MO,W - DAB=DIAZABUTADIENE) .1. ELECTRONIC ABSORPTION, RESONANCE RAMAN, INFRARED, C-13-NMR AND N-15-NMR SPECTRA [J].

STAAL, LH ;

STUFKENS, DJ ;

OSKAM, A .

INORGANICA CHIMICA ACTA, 1978, 26 (02) :255-262

[10] ALPHA-DIIMINES AS MONODENTATE OR BRIDGING LIGANDS - SYNTHESIS AND CHARACTERIZATION OF PALLADIUM(II) AND RHODIUM(I) DI(TERT-BUTYL)DIIMINE COMPLEXES [J].

VANDERPOEL, H ;

VANKOTEN, G ;

VRIEZE, K .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 135 (03) :C63-C65