REACTIVE ANNULENONES - A COMPARATIVE-STUDY

被引：15

作者：

GAVINA, F

COSTERO, AM

GONZALEZ, AM

机构：

[1] Departamento de Quimica Orgdnica, Facultad de Quimica, Universidad de Valencia, 46100 Burjassot, Valencia

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 07期

关键词：

D O I：

10.1021/jo00294a018

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two new and hitherto elusive annulenones, 3-phenylcyclopentadienone and bicyclo[3.3.0]octa-l(5),3,6-triene-2,8-dione, are reported. Their lifetimes and reactivities have been studied in comparison with those of the related annulenones cyclopentadienone and 4-phenylbicyclo[3.3.0]octa-l(5),3,6-triene-2,8-dione. The influence of structure and substituents on the stabilities of these species has thereby been established. © 1990, American Chemical Society. All rights reserved.

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页码：2060 / 2063

页数：4

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