MONOMERIC AND DIMERIC PRODUCTS OF PROTONATION OF DIOXOTETRACYANOMETALATES(IV) .1. COMPLEXES OF TUNGSTEN(IV)

被引：16

作者：

SAMOTUS, A

KANAS, A

DUDEK, M

机构：

[1] Institute of Chemistry, Jagiellonian University, Kraków

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 08期

关键词：

D O I：

10.1016/0022-1902(79)80470-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of tungsten(IV) complexes of formula Me3[WO(OH)(CN)4]xH2O and Me6[W2O3(CN)8]xH2O (where Me = Na, K) have been synthesized. The solids obtained were characterized by chemical analysis, thermogravimetric and differential thermal analysis, IR, Raman and visible spectrophotometry and magnetic susceptibility measurements. The analysis of the IR and Raman spectra has led to an assignment of the fundamental vibrations which was supported by studies of IR spectra of the deuterated and anhydrous salts. © 1979.

引用

页码：1129 / 1134

页数：6

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