SYNTHESIS OF SOLENOPSIN-B VIA STEREOSELECTIVE REDUCTION OF BICYCLIC N,O-KETALS

被引：30

作者：

KOTSUKI, H

KUSUMI, T

INOUE, M

USHIO, Y

OCHI, M

机构：

[1] Department of Chemistry, Faculty of Science, Kochi University, Kochi, 780, Akebono-cho

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 33期

关键词：

ENANTIOSELECTIVE SYNTHESIS; SOLENOPSIN-B; STEREOSELECTIVE REDUCTION; BICYCLIC N; O-KETALS; DIBALH;

D O I：

10.1016/S0040-4039(00)79891-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new enantionselective total synthesis of (-)-solenopsin B was described starting from L-glutamic acid as an optically active natural source, in which stereoselective reduction of bicyclic N,O-ketals with DIBALH was used as the key reaction step.

引用

页码：4159 / 4162

页数：4

共 22 条

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