A NOVEL MICROPOROUS MIXED-TRANSITION-METAL PHOSPHATE - HYDROTHERMAL SYNTHESIS, CHARACTERIZATION, AND STRUCTURE OF ZN2CO4(PO4)4(H2O)(5)CENTER-DOT-2H(2)O

被引：27

作者：

WHANG, DM

HUR, NH

KIM, K

机构：

[1] POHANG UNIV SCI & TECHNOL,DEPT CHEM,POHANG 790784,SOUTH KOREA

[2] POHANG UNIV SCI & TECHNOL,CTR BIOFUNCT MOLEC,POHANG 790784,SOUTH KOREA

[3] KOREA RES INST STAND & SCI,TAEJON 305600,SOUTH KOREA

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 12期

关键词：

D O I：

10.1021/ic00116a033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel microporous mixed-transition-metal phosphate Zn2Co4(PO4)(4)(H2O)(5).2H(2)O has been synthesized hydrothermally and structurally characterized by single crystal X-ray crystallography. It has a new open-framework structure containing unusually large ellipsoidal cavities which are connected with each other through 10-ring openings to form channels parallel to the a axis. The thermal and magnetic properties of the compound ale also presented.

引用

页码：3363 / 3366

页数：4

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