STUDIES ON JULIMYCINS .5. CONFIGURATIONS AND CONFORMATIONS OF JULICHROME Q1.3 AND ITS C9-EPIMER

被引:8
作者
TSUJI, N
NAGASHIMA, K
机构
[1] Shionogi Research Laboratory, Shionogi and Co., Ltd., Fukushima-ku, Osaka
关键词
D O I
10.1016/S0040-4020(01)82835-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The hydrolysis of 9-O-acetyl derivative of julichrome Q1·3 (I) gave the C9-epimer of I. The configuration of C9-OH of I has been assigned as β by the comparison of the spectroscopic properties of I and its C9-epimer. The conformations and intramolecular H-bonding aspects of both compounds are also discussed. © 1969.
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页码:3017 / +
页数:1
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