KINETIC-STUDY OF HYDROGEN TRANSFER OF OLEFINS UNDER CATALYTIC CRACKING CONDITIONS

被引：25

作者：

DESROCHETTES, BM

MARCILLY, C

GUEGUEN, C

BOUSQUET, J

机构：

[1] CTR RECH ELF SOLAIZE, F-69360 ST SYMPHORIEN DOZON, FRANCE

[2] ECOLE NATL SUPER PETR & MOTEURS, F-92506 RUEIL MALMAISON, FRANCE

来源：

APPLIED CATALYSIS | 1990年 / 58卷 / 01期

关键词：

D O I：

10.1016/S0166-9834(00)82277-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A kinetic study of hydrogen transfer and isomerization reactions has been carried out for cyclopentene and cyclohexene. For both cycloolefins, the limiting step of hydrogen transfer is the hydride ion transfer. Isomerization of cyclohexene is rate limited by the proton transfer from a methylcyclopentyl cation to a cycloolefin molecule. Decay parameters have been determined as a function of temperature. Activation energies have also been measured. © 1990.

引用

页码：35 / 52

页数：18

共 23 条

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