REGIOSPECIFIC FUNCTIONALIZATION OF BINOR-S BY A GIF TYPE OXIDATION SYSTEM

被引：14

作者：

BARTON, DHR ^{[1
]}

EATON, PE ^{[1
]}

LIU, WG ^{[1
]}

机构：

[1] UNIV CHICAGO,DEPT CHEM,CHICAGO,IL 60637

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 44期

关键词：

D O I：

10.1016/0040-4039(91)80142-S

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Under GoAgg(III) conditions, the saturated heptacyclic hydrocarbon Binor S which contains 12 tertiary and 2 secondary carbons, was regiospecifically oxidized to a single product, the ketone heptacyclo[8.4.0.0(2,7).0(3,5).0(4,8).0(9,13).0(12,14]tetradecane-6-one with good yield. This work represents the first example of a completely regiospecific oxidation of a methylene group into a ketone in the presence of so many saturated tertiary C-H bonds by a Gif type system.

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页码：6263 / 6264

页数：2

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