SYNTHESIS OF THE PSEUDOHALIDE-DINITROGEN COMPLEXES TRANS-[REX(N2)(PH2PCH2CH2PPH2)2] (X = NCS, NCO OR N3) AND CRYSTAL-STRUCTURES OF THE ISOTHIOCYANATE AND AZIDE COMPLEXES

被引：12

作者：

WANG, Y

DASILVA, JJRF

POMBEIRO, AJL

PELLINGHELLI, MA

TIRIPICCHIO, A

机构：

[1] INST SUPER TECN,CTR QUIM ESTRUTURAL,COMPLEXO I,AV ROVISCO PAIS,P-1096 LISBON,PORTUGAL

[2] UNIV PARMA,CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,IST CHIM GEN & INORGAN,I-43100 PARMA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 454卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83242-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The isothiocyanate-, isocyanate- and azide-dinitrogen complexes trans-[ReX(N2)(dppe)2] (1a, X = NCS; 1b, X = NCO; 1c, X = N3; dppe = Ph2PCH2CH2PPh2) have been prepared by reactions of NaX with trans-[ReCl(N2)(dppe)2]. The crystal structures for la and 1c are reported; la is the first dinitrogen-isothiocyanate complex to be structurally characterized.

引用

页码：211 / 216

页数：6

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