NAD(P)+-NAD(P)H MODELS .82. EFFECT OF MAGNESIUM-ION ON THE STEREOSPECIFICITY AND CONFORMATIONS AT THE GROUND AND TRANSITION-STATES OF THE REACTION

被引：26

作者：

OKAMURA, M

MIKATA, Y

YAMAZAKI, N

TSUTSUMI, A

OHNO, A

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 04期

关键词：

D O I：

10.1246/bcsj.66.1197

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conformations of 3-[methyl(alpha-methylbenzyl)carbamoyl]-1,2,4-trimethyl-1,4-dihydroquinoline ((4R)-Me3MQPH) in the presence and absence of magnesium ion have been studied. The major conformation at the ground state of Me3MQPH changes largely when this molecule forms a complex with a magnesium ion. The conformations at the ground and transition states will be discussed in relation to the stereospecificity of the reaction of this compound with quinones.

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页码：1197 / 1203

页数：7

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