NUCLEAR CONTRIBUTION TO HYPERPOLARIZABILITY OF POLYCONJUGATED COMPOUNDS - ROLE OF VIBRATIONAL INTENSITIES

被引:20
作者
DELZOPPO, M
CASTIGLIONI, C
VERONELLI, M
ZERBI, G
机构
[1] Dip. Chimica Industriale, Politecnico di Milano
关键词
D O I
10.1016/0379-6779(93)90535-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present absolute FT Raman intensity measurements on polyenic systems of various chain lengths in order to assess the validity of a semiclassical model, recently proposed, which stresses the importance of the nuclear contribution to the non linear optical response of a conjugated molecule in a static field, and relates the nuclear contribution to tau to the Raman intensities.
引用
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页码:3919 / 3926
页数:8
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